Biobased adhesives : sources, characteristics, and applications

This book contains 23 chapters covering the various ramifications of biobased adhesives. The chapters are written by world-class scientists and technologists actively involved in the arena of biobased adhesives. The book is divided into three parts: Part 1: Fundamental Aspects; Part 2: Classes of Bi...

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Bibliographic Details
Other Authors Dunky, Manfred (Editor), Mittal, K. L. (Editor)
Format Electronic eBook
LanguageEnglish
Published Hoboken, NJ : John Wiley & Sons, Incorporated, 2023.
SeriesAdhesion and adhesives.
Subjects
Adhesives.
elektronické knihy
electronic books
Online AccessFull text
ISBN9781394175406
139417540X
1394175396
9781394175390
9781394174638
1394174632
Physical Description1 online resource.

Cover

Table of Contents:
  • Cover
  • Title Page
  • Copyright Page
  • Contents
  • Preface
  • Part 1: Fundamental Aspects
  • Chapter 1 Introduction to Naturally-Based (Bio-) Adhesives
  • 1.1 Introduction
  • 1.2 Overview and Challenges For Adhesives Based on Natural Resources
  • 1.2.1 Combined Use of Synthetic and Naturally-Based Adhesives
  • 1.2.2 Overview on Adhesives Based on Natural Resources
  • 1.2.3 Requirements, Limitations, and Opportunities for Wood Adhesives Based on Natural Resources
  • 1.3 Biorefinery and Platform Chemicals
  • 1.4 Lignin as Raw Material for Platform Chemicals
  • 1.5 5-Hydroxymethylfurfural (5-HMF) as Platform Chemical
  • 1.6 Mimicking Nature
  • 1.7 Special Topics and Latest Developments
  • 1.8 Prospects
  • 1.9 Summary
  • General Literature on Biobased Adhesives
  • List of Abbreviations
  • References
  • Chapter 2 Adhesion Theories in Naturally-Based Bonding: Adhesion and Surface Issues with Naturally-Based Adhesives
  • 2.1 Introduction
  • 2.2 Adhesion Theories
  • 2.2.1 Mechanical Interlocking
  • 2.2.2 Electrostatic Mechanism
  • 2.2.3 Adsorption (Thermodynamic) or Wetting Mechanism
  • 2.2.4 Diffusion Mechanism
  • 2.2.5 Chemical (Covalent) Bonding Mechanism
  • 2.2.5.1 Hydrogen Bonding
  • 2.2.6 Acid-Base Theory
  • 2.2.7 Weak Boundary Layers
  • 2.2.8 Stickiness or Tackiness
  • 2.3 Protein Adhesives
  • 2.3.1 Animal-Sourced Proteins
  • 2.3.2 Plant Proteins
  • 2.4 Carbohydrate-Based Adhesives
  • 2.5 Plant or Wood-Based Extractives
  • 2.5.1 Rubber
  • 2.5.2 Resins
  • 2.5.2.1 Rosin
  • 2.5.2.2 Terpene Resins
  • 2.5.2.3 Tannins
  • 2.5.2.4 Gums
  • 2.6 Fats or Oils
  • 2.6.1 Tung Oil
  • 2.6.2 Linseed Oil
  • 2.6.3 Soybean Oil
  • 2.6.4 Castor Oil
  • 2.6.5 Miscellaneous Oils
  • 2.7 Summary
  • Acknowledgements
  • List of Abbreviations
  • References
  • Chapter 3 The Chemistry of Bioadhesives
  • 3.1 Introduction
  • 3.2 Carbohydrate Bioadhesives.
  • 3.3 Protein Bioadhesives
  • 3.4 Lignin-Based Bioadhesives
  • 3.5 Tannin-Based Bioadhesives
  • 3.5.1 Hydrolysable Tannins
  • 3.5.1.1 Gallo-Tannins
  • 3.5.1.2 Ellagi-Tannins
  • 3.5.2 Condensed Polyflavonoid Tannins
  • 3.5.3 Reactions of Condensed Flavonoid Tannins
  • 3.6 Other Bio-Adhesives for Wood Composites
  • 3.7 Summary
  • List of Abbreviations
  • References
  • Chapter 4 Biorefinery Products as Naturally-Based Key Raw Materials for Adhesives
  • 4.1 Biorefinery Systems
  • 4.1.1 History of Biomaterials
  • 4.1.2 Classification of Biorefinery Systems
  • 4.1.3 Biorefinery Processes
  • 4.1.3.1 Hydrothermal Processes
  • 4.1.3.2 Thermochemical Processes
  • 4.1.3.3 Chemical Processes
  • 4.1.3.4 Biochemical Processes
  • 4.1.3.5 Bacterial Processes
  • 4.1.4 Renewable Materials for Biorefinery
  • 4.1.4.1 Carbohydrates
  • 4.1.4.2 Lignin
  • 4.1.4.3 Triglycerides
  • 4.1.4.4 Mixed Organic Residues
  • 4.2 Biobased Materials
  • 4.2.1 Biobased Monomers
  • 4.2.2 Synthesis Methods
  • 4.2.2.1 L-3,4-Dihydroxyphenylalanine
  • 4.2.2.2 2-Pyrone-4,6-dicarboxylic acid
  • 4.3 Biobased Materials Suitable for Adhesives
  • 4.3.1 Additives
  • 4.3.2 Wood Adhesives
  • 4.3.3 Lignin-Based Adhesives
  • 4.3.4 Biorefinery Process of Kash
  • 4.3.5 Lignin-Phenol Adhesives
  • 4.3.5.1 Enzymatic Hydrolysis of Lignin
  • 4.3.5.2 Biorefinery Residues
  • 4.3.5.3 Phenol Replacement by Lignins
  • 4.3.6 Lignin-Epoxy Adhesives
  • 4.3.7 Lignosulfonates
  • 4.3.8 Tannins
  • 4.3.9 Protein-Based Adhesives
  • 4.4 Synthesis Methods for Biobased Adhesives
  • 4.4.1 Methylolated Wood-Derived Bio-Oil
  • 4.4.2 Biosynthesis of Lignin
  • 4.4.3 Soy-Based Adhesives
  • 4.4.4 Bisphenol A-Glycidyl Methacrylate Replacement
  • 4.5 Modification of Lignin for Better Performance
  • 4.5.1 Functionalization with Aromatic Compounds
  • 4.5.1.1 Functionalization of Lignin
  • 4.5.1.2 Phenolation of Lignin.
  • 4.5.2 Organosolv Lignin-Based Materials
  • 4.6 Pressure-Sensitive Adhesives
  • 4.6.1 Lignin as Filler
  • 4.6.2 Biobased Acrylic Compounds
  • 4.6.3 UV-Tunable Pressure-Sensitive Adhesives
  • 4.7 Summary
  • References
  • Chapter 5 Natural Aldehyde-Based Thermosetting Resins
  • 5.1 Introduction
  • 5.2 Aliphatic Aldehydes
  • 5.2.1 Acetaldehyde
  • 5.2.2 Glyoxal
  • 5.2.2.1 Glyoxalation of Lignin
  • 5.2.2.2 Glyoxylic Acid and Glyoxal
  • 5.2.2.3 Glyoxal and Glutaraldehyde
  • 5.2.2.4 Glyoxal and 5-Hydroxymethylfurfural (5-HMF)
  • 5.2.3 Dimethoxy-Ethanal (Dimethoxy-Acetaldehyde, DME)
  • 5.2.4 Propanal (Propionaldehyde)
  • 5.2.5 Butyraldehyde
  • 5.2.6 Isobutyraldehyde (Isobutanal)
  • 5.2.7 Succinaldehyde (Butandial)
  • 5.2.8 Glutar(di)aldehyde (GA) (Pentandial)
  • 5.3 Aldehydes Based on Cyclic Structures
  • 5.3.1 Furfural (Furfurylaldehyde)
  • 5.3.2 Furfuryl Alcohol (FA)
  • 5.3.3 5-Hydroxymethylfurfural (5-HMF) (see also Chapters 1 and 17)
  • 5.3.4 2,5-Diformylfuran (2,5-Furan-Dicarbaldehyde)
  • 5.3.5 Aromatic Aldehyde Precursors
  • 5.3.6 Polymers with Pendent Aldehyde Groups
  • 5.4 Summary
  • List of Abbreviations
  • References
  • Chapter 6 Natural Crosslinkers for Naturally-Based Adhesives
  • 6.1 Introduction
  • 6.2 Crosslinking Reactions
  • 6.2.1 Proteins
  • 6.2.2 Tannins
  • 6.2.3 Carbohydrates
  • 6.2.4 Lignins
  • 6.3 Aliphatic Aldehydes as Crosslinkers
  • 6.3.1 Formaldehyde
  • 6.3.2 Higher Aldehydes
  • 6.3.3 Glyoxal
  • 6.3.4 Glutaraldehyde
  • 6.3.5 Higher Aliphatic Aldehydes
  • 6.4 Cyclic and Aromatic Aldehydes as Crosslinkers
  • 6.4.1 Furfural
  • 6.4.2 5-Hydroxymethylfurfural (5-HMF)
  • 6.4.3 Non-Volatile Aldehydes from Carbohydrates
  • 6.5 Crosslinkers Prepared from Biomass
  • 6.5.1 Furfuryl Alcohol
  • 6.5.2 Extracts as Crosslinkers
  • 6.5.3 Glycerol Diglycidyl Ether (GDE), Glycerol Polyglycidyl Ether (GPE), and Ethylene Glycol Diglycidyl Ether (EGDE).
  • 6.5.4 Triglycidylamine (TGA)
  • 6.5.5 Diethylene-Triamine (DETA)
  • 6.5.6 Citric Acid
  • 6.6 Synthetic Crosslinkers
  • 6.6.1 Polyamidoamine-Epichlorohydrin (PAE) Resins
  • 6.6.2 Epoxy Resins
  • 6.6.3 Polyethylenimine (PEI)
  • 6.6.4 Polyamidoamine (PADA)
  • List of Abbreviations
  • References
  • Chapter 7 Curing and Adhesive Bond Strength Development in Naturally-Based Adhesives
  • 7.1 Introduction
  • 7.2 Curing Monitoring Techniques
  • 7.2.1 Gel Time Test
  • 7.2.2 Differential Scanning Calorimetry (DSC)
  • 7.2.3 Thermogravimetric Analysis (TGA)
  • 7.2.4 Dielectric Analysis (DEA)
  • 7.3 Bond Strength Development Monitoring Techniques
  • 7.3.1 Dynamic Mechanical Analysis (DMA)
  • 7.3.2 Thermomechanical Analysis (TMA)
  • 7.3.3 Automated Bonding Evaluation System (ABES)
  • 7.3.4 Tensile-Shear Strength
  • 7.4 Curing Mechanisms in Naturally-Based Adhesives
  • 7.4.1 Tannin-Based Adhesives
  • 7.4.2 Lignin-Based Adhesives
  • 7.4.3 Soy-Based Adhesives
  • 7.4.4 Sucrose-Based Adhesives
  • 7.4.5 Starch-Based Adhesives
  • 7.4.6 Liquefied Wood (LW)-Based Adhesives
  • 7.5 Summary
  • Acknowledgements
  • List of Abbreviations
  • References
  • Chapter 8 Mimicking Nature: Bio-Inspired Adhesives
  • 8.1 Introduction
  • 8.2 Improvement of Adhesive Performance
  • 8.3 Underwater Adhesives (Wet Application Adhesives)
  • 8.4 Detechable Bonding and Self-Healing Polymers
  • 8.5 Medical Applications
  • 8.6 Summary
  • List of Abbreviations
  • References
  • Part 2: Classes of Biobased Adhesives
  • Chapter 9 Protein Adhesives
  • Composition, Structure and Performance
  • 9.1 Introduction
  • 9.2 Composition of Proteins
  • 9.3 Types, Sources, Processing, and Properties of Proteins
  • 9.3.1 Collagen (Animal)
  • 9.3.2 Globular (Plant)
  • 9.3.3 Globular (Milk)
  • 9.3.4 Globular (Egg)
  • 9.3.5 Globular (Blood)
  • 9.3.6 Other Protein Sources.
  • 9.4 Conclusion (Future of Protein Adhesives) and Summary
  • List of Abbreviations
  • References
  • Chapter 10 Carbohydrates (Polysaccharides) as Adhesives
  • 10.1 Introduction
  • 10.2 Cellulose Derivatives
  • 10.3 Starch-Based Adhesives
  • 10.4 Dextrin
  • 10.5 Natural Gums
  • 10.6 Chitosan
  • 10.7 Summary and Prospects
  • Acknowledgements
  • List of Abbreviations
  • References
  • Chapter 11 Natural Polymer-Based Adhesives
  • 11.1 Introduction
  • 11.2 Natural Rubber (NR)-Based Adhesives
  • 11.2.1 Introduction to NR-Based Adhesives
  • 11.2.2 NR-Based Wood Adhesives
  • 11.2.3 NR-Based Pressure-Sensitive Adhesives
  • 11.2.4 NR-Based Adhesives in Leather, Rubber, Textile and Metal Bonding Applications
  • 11.3 Poly(lactic acid) (PLA)-Based Wood Adhesives
  • 11.3.1 Introduction to PLA-Based Adhesives
  • 11.3.2 PLA-Based Wood Adhesives
  • 11.3.3 PLA-Based Hot-Melt Adhesives
  • 11.3.4 PLA-Based Adhesives for Metal Bonding
  • 11.4 Chitosan-Based Adhesives
  • 11.4.1 Introduction to Chitosan-Based Adhesives
  • 11.4.2 Chitosan-Based Wood Adhesives
  • 11.5 Summary
  • List of Abbreviations
  • References
  • Chapter 12 Epoxy Adhesives from Natural Materials
  • 12.1 Introduction and Morphology
  • 12.2 Basic Properties of Epoxies
  • 12.3 Epoxy Synthesis
  • 12.4 Epoxy Curing
  • 12.4.1 One-Component Epoxies
  • 12.4.2 Two-Component Epoxies
  • 12.5 Aromatic Epoxies
  • 12.5.1 Aromatic Bis-Phenol Epoxies
  • 12.5.2 Aromatic Novolac Epoxies
  • 12.5.3 Biobased Aromatic Epoxies from Polyphenols, Tannins, Cardanol, and Lignin
  • 12.5.4 Aromatic Epoxies from Lignin and Woody Biomass
  • 12.6 Aliphatic Epoxies
  • 12.6.1 Aliphatic Epoxies from Vegetable Oils
  • 12.6.2 Aliphatic Epoxies from Sugars
  • 12.6.3 Aliphatic Epoxies from Terpenoids
  • 12.6.4 Other Aliphatic Epoxies
  • 12.7 Hardeners
  • 12.7.1 Amines
  • 12.7.1.1 Aliphatic Amines
  • 12.7.1.2 Biobased Aliphatic Amines.

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