Rheology of polymeric systems : principles and applications

• Main Authors: Carreau, Pierre J. (Author), De Kee, D. (Author), Chhabra, R. P. (Author)
• Format: Electronic eBook
• Language: English
• Published: Munich : Hanser Publishers, 2021.
• Edition: 2nd edition.
• Subjects: Polymers > Rheology > Textbooks.; Polymers > Rheology.; elektronické knihy; electronic books
• ISBN: 9781569907238; 1569907234; 9781569907221; 1569907226
• Physical Description: 1 online resource (645 pages)

"Rheology is applied extensively in polymer, chemical, food processing, and related industries. This book combines the basic concepts and applications by presenting a balanced overview of the principles. With simplified analysis of complex problems, the textbook format provides easy understandi...

Table of Contents:

• Intro
• Preface
• Contents
• 1 Introduction
• 1.1 Definitions and Classification
• 1.1.1 Purely Viscous or Inelastic Material
• 1.1.2 Perfectly Elastic Material
• 1.1.3 Viscoelastic Material
• 1.2 Non-Newtonian Phenomena
• 1.2.1 The Weissenberg Effect
• 1.2.2 Entry Flow, Extrudate Swell, Melt Fracture, and Vibrating Jet
• 1.2.3 Recoil
• 1.2.4 Open Syphon
• 1.2.5 Antithixotropic Effect
• 1.2.6 Drag Reduction
• 1.2.7 Hole Pressure Error
• 1.2.8 Mixing
• 1.2.9 Bubbles, Spheres, and Coalescence
• 2 Material Functions and Generalized Newtonian Fluids
• 2.1 Material Functions
• 2.1.1 Simple Shear Flow
• 2.1.2 Sinusoidal Shear Flow
• 2.1.3 Transient Shear Flows
• 2.1.4 Elongational Flow
• 2.2 Generalized Newtonian Models
• 2.2.1 Generalized Newtonian Fluid
• 2.2.2 The Power-Law Model
• 2.2.3 The Ellis Model (Bird, Armstrong, and Hassager, 1987)
• 2.2.4 The Carreau Model (1972)
• 2.2.5 The Cross-Williamson Model (1965)
• 2.2.6 The Four-Parameter Carreau Model (Carreau et al., 1979b)
• 2.2.7 The De Kee Model (1977)
• 2.2.8 The Carreau-Yasuda Model (Yasuda, 1979)
• 2.2.9 The Bingham Model (1922)
• 2.2.10 The Casson Model (1959)
• 2.2.11 The Herschel-Bulkley Model (1926)
• 2.2.12 The De Kee-Turcotte Model (1980)
• 2.2.13 The Papanastasiou Model (1987)
• 2.2.14 The Zhu-Kim-De Kee Model (2005)
• 2.2.15 Viscosity Models for Complex Flow Situations.
• 2.3 Thixotropy, Rheopexy, and Hysteresis
• 2.4 Relations Between Material Functions
• 2.5 Temperature, Pressure, and Molecular Weight Effects
• 2.5.1 Effect of Temperature on Viscosity
• 2.5.2 Effect of Pressure on Viscosity
• 2.5.3 Effect of Molecular Weight on Viscosity
• 2.6 Problems
• 2.6.1 Viscosity Data of a PIB Solutiona
• 2.6.2 Viscosity Data of a CMC Solutiona
• 2.6.3 The Ellis Modela
• 2.6.4 Viscosity Data for a PS Solutionb
• 2.6.5 Rheological Behavior of Drilling Mudsb
• 2.6.6 The Cross-Williamson Modelb
• 2.6.7 Viscosity-Molecular Weight Relationshipb
• 3 Rheometry
• 3.1 Capillary Rheometry
• 3.1.1 Rabinowitsch Analysis
• 3.1.2 End Effects or Bagley Correction
• 3.1.3 Mooney Correction
• 3.1.4 Intrinsic Viscosity Measurements
• 3.2 Coaxial-Cylinder Rheometers
• 3.2.1 Calculation of Viscosity
• 3.2.2 End-Effect Corrections
• 3.2.3 Normal Stress Determination
• 3.3 Cone-and-Plate Geometry
• 3.3.1 Viscosity Determination
• 3.3.2 Normal Stress Determination
• 3.3.3 Inertial Effects
• 3.3.4 Criteria for Transient Experiments
• 3.4 Concentric-Disk Geometry
• 3.4.1 Viscosity Determination
• 3.4.2 Normal Stress Difference Determination
• 3.5 Yield Stress Measurements
• 3.5.1 Yield Stress Measurement Methods
• 3.6 Problems
• 3.6.1 Rabinowitsch-Type Analysisa
• 3.6.2 Rabinowitsch Analysis for a Yield Stress Fluidb
• 3.6.3 Viscosity of a High-Density Polyethylenea
• 3.6.4 Cone-and-Plate Flowb
• 3.6.5 Parallel-Plate Rheometerb
• 3.6.6 Falling-Cylinder Viscometerb
• 3.6.7 Weissenberg Effecta.