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Chemistry of silica and zeolite-based materials
synthesis, characterization and applications
Chemistry of Silica and Zeolite-Based Materials covers a wide range of topics related to silica-based materials from design and synthesis to applications in different fields of science and technology. Since silica is transparent and inert to the light, it is a very attractive host material for constructing artificial photosynthesis systems. As an earth-abundant oxide, silica is an ideal and basic material for application of various oxides, and the science and technology of silica-based materials are fundamentally important for understanding other oxide-based materials. The book examines nanosolvation and confined molecules in silica hosts, catalysis and photocatalysis, photonics, photosensors, photovoltaics, energy, environmental sciences, drug delivery, and health. Written by a highly experienced and internationally renowned team from around the world, Chemistry of Silica and Zeolite-Based Materials is ideal for chemists, materials scientists, chemical engineers, physicists, biologists, biomedical sciences, environmental scientists, toxicologists, and pharma scientists. --- "The enormous versatility of silica for building a large variety of materials with unique properties has been very well illustrated in this book. The reader will be exposed to numerous potential applications of these materials - from photocatalytic, optical and electronic applications, to chemical reactivity in confined spaces and biological applications. This book is of clear interest not only to PhD students and postdocs, but also to researchers in this field seeking an understanding of the possible applications of meso and microporous silica-derived materials."--Professor Avelino Corma, Institute of Chemical Technology (ITQ-CSIC) and Polytechnical University of Valencia, Spain
Front Cover; Chemistry of Silica and Zeolite-Based Materials; Copyright Page; Contents; List of Contributors; About the Editors; Preface; 1 Synthesis and Applications of Periodic Mesoporous Organosilicas; 1.1 Introduction; 1.2 Synthesis of Periodic Mesoporous Organosilicas; 1.2.1 Fundamentals of Periodic Mesoporous Organosilica Synthesis; 1.2.2 Functional Periodic Mesoporous Organosilicas; 1.2.3 Control of the Arrangement of Organic Moieties in the Pore Walls; 1.3 Applications; 1.3.1 Light-Harvesting Antennae; 1.3.2 Periodic Mesoporous Organosilica-Based Photocatalysis
1.3.3 Hole-Transporting Properties and Photovoltaic Devices1.3.4 Substrates for Laser Desorption/Ionization Mass Spectrometry; 1.3.5 Solid Supports for Metal Complex Catalysts; 1.3.5.1 Phenylene-Periodic Mesoporous Organosilica; 1.3.5.2 Phenylpyridin-Periodic Mesoporous Organosilica; 1.3.5.3 2,2'-Bipyridine-Periodic Mesoporous Organosilica; 1.3.5.4 Catalysis of Well-Defined Metal Complexes on 2,2'-Bipyridine-Periodic Mesoporous Organosilica; 1.4 Conclusion and Outlook; References; 2 Silica Hosts for Acid and Basic Organosilanes: Preparation, Characterization, and Application in Catalysis
2.1 Introduction2.2 Functionalization of Mesoporous Silicas by Organosilanes Containing Acidic Groups; 2.2.1 Hybrid Materials Containing Strong -SO3H Acidic Centers; 2.2.1.1 Different Ways for Preparation of Functionalized Materials; 2.2.1.2 The Role of Additives in Silica Support; 2.2.1.3 Characterization of Surface Properties; 2.2.1.4 Application in Catalysis; 2.2.2 Hybrid Materials Containing Moderate Acidic -PO3H2 and Weak Acidic -COOH Groups; 2.2.2.1 Preparation and Characterization; 2.2.2.2 Application in Catalysis
2.3 Functionalization of Mesoporous Silicas by Organosilanes Containing Basic Centers2.3.1 Preparation of Mesoporous Silicas Functionalized With Basic Species Containing Nitrogen; 2.3.2 Characterization of Surface Properties of Hybrid Materials Containing Basic Species; 2.3.3 Application in Catalysis; 2.4 Multifunctional Catalysts Based on Amino-Grafted Silica Hybrid Materials; 2.4.1 Base-BrØnsted Acid Pairs on Silica Surface; 2.4.2 Base-Lewis Acid Pairs on Silica Surface; 2.4.3 Base-Redox Pairs on Silica Surface; 2.4.4 Trifunctional Mesoporous Silica Containing Amine
2.5 Transition Metals Anchored on Mesoporous Silicas Functionalized With Organosilanes2.5.1 Location of Organosilane; 2.5.2 Position of Metal Particles and Metal Dispersion; 2.5.3 Role of Mature of Functional Group in Organosilane; 2.6 Concluding Remarks; Acknowledgments; References; 3 Catalytic Interconversion of Sugars with Zeolite and Zeotype Materials; 3.1 Introduction; 3.2 Isomerization of Glucose; 3.2.1 Sn-Modified Zeolite Catalysts; 3.2.2 Other Zeolite Catalysts; 3.3 Isomerization of Xylose; 3.4 Isomerization of Erythrose; 3.5 Isomerization of Dihydroxyacetone; 3.5.1 Sn-Beta Zeolite
edited by Abderrazzak Douhal, Masakazu Anpo.
Plný text je dostupný pouze z IP adres počítačů Univerzity Tomáše Bati ve Zlíně nebo vzdáleným přístupem pro zaměstnance a studenty
Includes bibliographical references and index.
Chemical, Physical and Biological Aspects of Confined Systems ; 2