http://www.loc.gov/mods/v3 http://www.loc.gov/standards/mods/v3/mods-3-2.xsd
Applications in Separations and Catalysis
Focusing on applications in separation, adsorption and catalysis, this handbook underlines the importance of this hot and exciting topic. It provides an excellent insight into the synthesis and modification of MOFs, their synthesis on an industrial scale, their use as CO2 and chemical warfare adsorbers, and the role of defects in catalysis. In addition, the authors treat such new aspects as biocatalysis and applications in photocatalysis and optoelectronic devices.
Cover; Title Page; Copyright; Contents; Preface; Chapter 1 The Stability ofÂ Metalâ#x80;#x93;Organic Frameworks; 1.1 Introduction; 1.2 Chemical Stability; 1.2.1 Strengthening theÂ Coordination Bond; 1.2.2 Protecting theÂ Coordination Bond; 1.3 Thermal Stability; 1.4 Mechanical Stability; 1.5 Concluding Remarks; Acknowledgments; References; Chapter 2 Tuning theÂ Properties ofÂ Metalâ#x80;#x93;Organic Frameworks by Post-synthetic Modification; 2.1 Introduction; 2.2 Post-synthetic Modification Reactions; 2.2.1 Covalent Post-synthetic Modification; 2.2.2 Inorganic Post-synthetic Modification.
2.2.3 Extent of theÂ Reaction2.3 PSM forÂ Enhanced Gas Adsorption andÂ Separation; 2.3.1 PSM forÂ Carbon Dioxide Capture andÂ Separation; 2.3.2 PSM forÂ Hydrogen Storage; 2.4 PSM forÂ Catalysis; 2.4.1 Catalysis withÂ MOFs Possessing Metal Active Sites; 2.4.2 Catalysis withÂ MOFs containingÂ Reactive Organic Functional Groups; 2.4.3 Catalysis withÂ MOFs asÂ Host Matrices; 2.5 PSM forÂ Sequestration andÂ Solution Phase Separations; 2.5.1 Metal Ion Sequestration; 2.5.2 Anion Sequestration; 2.5.3 Removal ofÂ Organic Molecules fromÂ Solution; 2.6 PSM forÂ Biomedical Applications.
2.6.1 Therapeutic MOFs andÂ Biosensors2.6.2 PSM by Change ofÂ Physical Properties; 2.7 Post-synthetic Cross-Linking ofÂ Ligands inÂ MOF Materials; 2.7.1 Pre-synthetically Cross-Linked Ligands; 2.7.2 Post-synthetic Cross-Linking ofÂ MOF Linkers; 2.7.3 Post-synthetically Modifying theÂ Nature ofÂ Cross-Linked MOFs; 2.8 Conclusions; References; Chapter 3 Synthesis ofÂ MOFs at theÂ Industrial Scale; 3.1 Introduction; 3.2 MOF Patents fromÂ Academia versus theÂ Industrial Approach; 3.3 Industrial Approach toÂ MOF Scale-up; 3.4 Examples ofÂ Scaled-up MOFs; 3.5 Industrial Synthetic Routes toward MOFs.
3.5.1 Electrochemical Synthesis3.5.2 Continuous Flow; 3.5.3 Mechanochemistry andÂ Extrusion; 3.6 Concluding Remarks; Acknowledgments; List of Abbreviations; References; Chapter 4 From Layered MOFs toÂ Structuring at theÂ Meso-/Macroscopic Scale; 4.1 Introduction; 4.2 Designing Bidimensional Networks; 4.3 Methodological Notes Regarding Characterization ofÂ 2D Materials; 4.3.1 Morphological andÂ Structural Characterization; 4.3.2 Spectroscopic andÂ Diffractometric Characterization; 4.4 Preparation andÂ Characterization; 4.4.1 Bottom-Up Approaches; 4.4.2 Miscellaneous; 4.4.3 Top-Down Approaches.
4.5 Properties andÂ Potential Applications4.5.1 Gas Separation; 4.5.2 Electronic Devices; 4.5.3 Catalysis; 4.6 Conclusions andÂ Perspectives; Acknowledgments; References; Chapter 5 Application of Metalâ#x80;#x93;Organic Frameworks (MOFs) for CO2 Separation; 5.1 Introduction; 5.2 Factors Influencing theÂ Applicability ofÂ MOFs forÂ CO2 Capture; 5.2.1 Open Metal Sites; 5.2.2 Amine Grafting onÂ MOFs; 5.2.3 Effects ofÂ Organic Ligand; 5.3 Current Trends inÂ CO2 Separation Using MOFs; 5.3.1 Ionic Liquids/MOF Composites; 5.3.2 MOF Composites forÂ CO2 Separation; 5.3.3 Water Stability ofÂ MOFs.
edited by Hermenegildo Garcia and Sergio Navalon.
Plný text je dostupný pouze z IP adres počítačů Univerzity Tomáše Bati ve Zlíně nebo vzdáleným přístupem pro zaměstnance a studenty
[Place of publication not identified] : Wiley-VCH, 2018