Reactive polymers fundamentals and applications : a concise guide to industrial polymers
Reactive Polymers: Fundamentals and Applications: A Concise Guide to Industrial Polymers, Third Edition introduces engineers and scientists to a range of reactive polymers and then details their applications and performance benefits. Basic principles and industrial processes are described for each c...
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| Main Author | |
|---|---|
| Format | Electronic eBook |
| Language | English |
| Published |
Amsterdam :
William Andrew is an imprint of Elsevier,
2018.
|
| Edition | Third edition. |
| Series | PDL handbook series.
|
| Subjects | |
| Online Access | Full text |
| ISBN | 9780128145104 0128145102 9780128145098 0128145099 |
| Physical Description | 1 online resource : illustrations |
Cover
Table of Contents:
- Front Cover
- Reactive Polymers: Fundamentals and Applications
- Copyright
- Contents
- Preface
- Preface to Third Edition
- Preface to Second Edition
- Preface to First Edition
- How to Use this Book
- Index
- Acknowledgments
- 1 Unsaturated Polyester Resins
- 1.1 History
- 1.2 Monomers
- 1.2.1 Monomers for an Unsaturated Polyester
- 1.2.1.1 Alcohol Components
- 1.2.1.2 Acid and Anhydride Components
- 1.2.1.3 Amine Modi ers
- 1.2.1.4 Dicyclopentadiene
- 1.2.2 Vinyl Monomers
- 1.2.2.1 Styrenes
- 1.2.2.2 Acrylates and Methacrylates
- 1.2.2.3 Vinyl Ethers
- 1.2.2.4 Other Vinyl Monomers
- 1.2.2.5 Biobased Vinyl Oligomers
- 1.2.3 Specialities
- 1.2.3.1 Flame Retardant Phosphorous Containing Monomers
- 1.2.3.2 Monomers for Waterborne Unsaturated Polyesters
- 1.2.3.3 Low Emission Modi ers
- 1.2.3.4 Epoxide-Based Unsaturated Polyesters
- 1.2.3.5 Isocyanates
- 1.2.3.6 o-Carboxy Phthalanilic Acid
- 1.2.3.7 Modi ed Plant Oils
- 1.2.4 Synthesis
- 1.2.4.1 Kinetics of Polyesteri cation
- 1.2.4.2 Sequence Distribution of Double Bonds
- 1.2.4.3 Enzyme-Catalyzed Polymerization
- 1.2.4.4 Post Polymerization Modi cation
- 1.2.5 Manufacture
- 1.3 Special Additives
- 1.3.1 Inhibitors
- 1.3.1.1 Shelf Life Extension
- 1.3.2 Thickeners
- 1.3.2.1 Multivalent Salts
- 1.3.2.2 Thixotropic Additives
- 1.3.2.3 Organoclays
- 1.3.3 Emission Suppressants
- 1.3.4 Fillers
- 1.3.4.1 Inorganic Fillers
- 1.3.4.2 Wood Flour
- 1.3.4.3 Rubber
- 1.3.4.4 Nanocomposites
- 1.3.4.5 Nanoclays
- 1.3.4.6 Carbon Nanotubes
- 1.3.5 Reinforcing Materials
- 1.3.5.1 Glass Fibers
- 1.3.5.2 Wollastonite
- 1.3.5.3 Carbon Fibers
- 1.3.5.4 Natural Fibers
- 1.3.6 Additives for Molding Applications
- 1.3.6.1 Mixture Stabilizing Additives
- 1.3.6.2 Mold Release Agents
- 1.3.7 Low-Pro le Additives
- 1.3.8 Interpenetrating Polymer Networks.
- 1.3.8.1 Poly(urethane)s
- 1.3.8.2 Epoxides
- 1.3.8.3 Vinylester Resins
- 1.3.8.4 Phenolic Resins
- 1.3.8.5 Organic-Inorganic Hybrids
- 1.3.9 Poly(urethane) Hybrid Networks
- 1.3.9.1 UV Stabilizers
- 1.3.10 Flame Retardants
- 1.3.10.1 Flame Retardant Additives
- 1.3.10.2 Flame Retardant Polyester Components
- 1.3.10.3 Flame Retardant Vinyl Monomers
- 1.3.10.4 Foaming Agent
- 1.3.11 Production Data
- 1.4 Curing
- 1.4.1 Initiator Systems
- 1.4.1.1 In Situ Generated Peroxides
- 1.4.1.2 Functional Peroxides
- 1.4.1.3 Photoinitiators
- 1.4.2 Low Temperature Curing
- 1.4.3 Promoters
- 1.4.4 Initiator Promoter Systems
- 1.4.5 Polymerization
- 1.4.5.1 Kinetics of Curing
- 1.4.5.2 Catalysis by Nanoparticles
- 1.4.5.3 Phase Separation
- 1.5 Properties
- 1.5.1 Structure Properties Relationships
- 1.5.2 Hydrolytic Stability
- 1.5.3 Recycling
- 1.5.3.1 Microwave Radiation
- 1.5.3.2 Poly(ethylene terephthalate) Waste Products
- 1.5.3.3 Cured Unsaturated Polyester Resin Waste
- 1.6 Applications and Uses
- 1.6.1 Decorative Specimens
- 1.6.2 Polyester Concrete
- 1.6.3 Reinforced Materials
- 1.6.4 Pre-accelerated Resin Compositions
- 1.6.5 Coatings
- 1.6.5.1 Powder Coatings
- 1.6.5.2 Coatings with Vinyl Ethers
- 1.6.5.3 Coatings with Blister Resistance
- 1.6.5.4 Corrosion Protection of Carbon Steel Oil Pipelines
- 1.6.5.5 Impregnation Coatings
- 1.6.6 Medical Uses
- 1.6.6.1 Adsorption of Pharmaceuticals
- 1.6.6.2 Braille Blocks
- 1.7 Special Formulations
- 1.7.1 Vinyl Ester Resins
- 1.7.2 Electrically Conductive Resins
- 1.7.3 Poly(e-caprolactone)-per uoropolyether Copolymers
- 1.7.4 Toner Compositions
- 1.7.5 Pour Point Depressants
- 1.7.6 Biodegradable Polyesters
- 1.7.7 Neutron Shielding
- 1.7.8 Bone Cement
- 1.7.9 Compatibilizers
- 1.7.10 Reactive Melt Modi cation of Poly(propylene).
- 1.7.11 Encapsulation of Electric and Electronic Parts
- 1.7.12 Lamp Re ector
- 1.7.13 LED Re ector
- 1.7.14 Toner Resins
- References
- 2 Poly(urethane)s
- 2.1 History
- 2.2 Monomers
- 2.2.1 Diisocyanates
- 2.2.1.1 Toluene Diisocyanate
- 2.2.1.2 Diphenylmethane diisocyanate
- 2.2.1.3 Aliphatic Diisocyanates
- 2.2.1.4 Modi ed Diisocyanates
- 2.2.1.5 Enzymatic Synthesis of Poly(urethane)s
- 2.2.1.6 Synthesis of Urethanes via Carbonate Esters
- 2.2.2 Polyols
- 2.2.2.1 Polyether Polyols
- 2.2.2.2 Polyester Polyols
- 2.2.3 Other Polyols
- 2.2.3.1 Hydrocarbon Polyols
- 2.2.3.2 Polythioether Polyols
- 2.2.3.3 Polyacetal Polyols
- 2.2.3.4 Acrylic Polyols
- 2.2.3.5 Lique ed Wood
- 2.2.3.6 Natural Hydroxyl Compounds
- 2.2.4 Polyamines
- 2.2.5 Chain Extenders
- 2.2.6 Catalysts
- 2.2.7 Blowing
- 2.2.7.1 Gelling and Crosslinking
- 2.2.7.2 Tertiary Amine Catalysts
- 2.2.7.3 Mechanisms of Tertiary Amine Catalysts
- 2.2.7.4 Reactive Catalysts
- 2.2.7.5 Anionic Catalysts
- 2.2.7.6 Organometallic Catalysts
- 2.3 Special Additives
- 2.3.1 Fillers
- 2.3.1.1 Cork
- 2.3.1.2 Agar
- 2.3.1.3 Carbon Nanomaterials
- 2.3.1.4 Rectorite Nanocomposites
- 2.3.1.5 Zeolite
- 2.3.1.6 Iron Particles
- 2.3.2 Reinforcing Materials
- 2.3.2.1 Cellulose Nano bers
- 2.3.2.2 Nanosilica Particles
- 2.3.2.3 Layered Silicate Nanocomposites
- 2.3.2.4 Nanoclays
- 2.3.2.5 Nano Carbonate Particles
- 2.3.2.6 Amino-Functionalized Carbon Nano bers
- 2.3.2.7 Coated Fabric
- 2.3.3 Flame Retardants
- 2.3.3.1 Poly(epichlorohydrin)
- 2.3.3.2 Polyphosphates
- 2.3.3.3 Expandable Graphite
- 2.3.3.4 Charring Agents
- 2.4 Curing
- 2.4.1 Recycling
- 2.4.1.1 Solvolysis
- 2.4.1.2 Ultrasonic Reactor
- 2.4.1.3 Polyacetal-Modi ed Poly(urethane)s
- 2.4.1.4 Production Wastes
- 2.4.1.5 Agricultural Wastes
- 2.4.1.6 Waste Water.
- 2.4.1.7 Urea-Free Compositions
- 2.5 Properties
- 2.5.1 Mechanical Properties
- 2.5.2 Thermal Properties
- 2.5.3 Weathering Resistance
- 2.6 Applications and Uses
- 2.6.1 Casting
- 2.6.2 Foams
- 2.6.2.1 Nano Tin Oxide Composites
- 2.6.2.2 Conductive Foams
- 2.6.2.3 Foams for Carbon Dioxide Capture
- 2.6.2.4 Foams from Recycled Poly(urethane)
- 2.6.3 Membranes
- 2.6.3.1 Graphene Oxide/Polyurethane Nanocomposite
- 2.6.4 Passive Air Samplers
- 2.6.5 Identi cation Tagging
- 2.7 Special Formulations
- 2.7.1 Interpenetrating Networks
- 2.7.1.1 Water Desalination
- 2.7.2 Methacrylate Copolymers
- 2.7.3 Grafting with Isocyanates
- 2.7.3.1 Chitosan
- 2.7.4 Composites for Thermal Energy Storage
- 2.7.5 Coatings
- 2.7.5.1 Waterborne Surface Coating Material
- 2.7.5.2 Coatings for Golf Balls
- 2.7.6 Medical Applications
- 2.7.6.1 Siloxane-Based Poly(urethane)s
- 2.7.6.2 Blood Compatibility
- 2.7.6.3 Degradable Poly(urethane)s
- 2.7.6.4 Polyurethanes with Controlled Hydrophobic to Hydrophilic Ratio
- 2.7.6.5 Encapsulation of ß-Sitosterol
- 2.7.6.6 Polyurethane Keratin Silver Nanoparticle Mats
- 2.7.6.7 Prevention of Poly(urethane) Heart Valve Cusp Calci cation
- 2.7.6.8 Controlled Release
- 2.7.6.9 Continuous Glucose Sensors
- 2.7.7 Solid State Fermentation
- 2.7.8 Catalysis of the Knoevenagel Reaction
- 2.7.9 Oil Spill Cleanup
- 2.7.10 Bio ltration of Organic Compounds
- 2.7.11 Footwear
- 2.7.12 Waterborne Poly(urethane)s
- 2.7.13 Elastic Conductive Filaments
- 2.7.14 Non-Isocyanate Poly(urethane) Systems
- 2.7.15 Biobased Networks
- 2.7.16 Stamps
- 2.7.17 Nanowire Electrodes
- 2.7.18 Electromagnetic Interference Shielding
- 2.7.19 Electrically Conductive Adhesives
- 2.7.20 Ceramic Foams
- 2.7.20.1 Heat Press Molding
- 2.7.21 Adhesion Modi cation
- 2.7.22 Electrolytes
- 2.7.23 3 D Printing
- References.
- 3 Epoxy Resins
- 3.1 History
- 3.2 Monomers
- 3.2.1 Epoxides
- 3.2.1.1 Epoxide Equivalent Weight
- 3.2.2 Phenols
- 3.2.3 Specialities
- 3.2.3.1 Hyperbranched Polymers
- 3.2.3.2 Liquid Crystalline Epoxide Resins
- 3.2.3.3 Bio-Based Monomers
- 3.2.4 Manufacture
- 3.2.4.1 Epoxides
- 3.2.4.2 Glycidyl Ethers
- 3.2.4.3 Fluorinated Epoxides
- 3.2.4.4 Epoxy Resins with Disul de Moieties
- 3.2.4.5 Cycloaliphatic Epoxy Compounds
- 3.2.4.6 Supramolecular Polymers
- 3.3 Special Additives
- 3.3.1 Crosslinking Agents
- 3.3.2 Toughening Agents
- 3.3.2.1 Polyvinyl Compounds
- 3.3.2.2 Polycondensates
- 3.3.2.3 Liquid Rubbers
- 3.3.2.4 Silicone Elastomers
- 3.3.2.5 Rubbery Epoxy Compounds
- 3.3.2.6 Phase Separation
- 3.3.2.7 Preformed Particles
- 3.3.2.8 Inorganic Particles
- 3.3.3 Antiplasticizers
- 3.3.4 Lubricants
- 3.3.5 Adhesion Improvers
- 3.3.6 Conductivity Modi ers
- 3.3.7 Accelerators
- 3.3.7.1 Piperazine Compounds
- 3.3.7.2 Semicarbazones
- 3.3.8 Reinforcing Materials
- 3.3.8.1 Composites and Laminates
- 3.3.8.2 Nanocomposites
- 3.3.9 Graphene
- 3.3.9.1 In Situ Exfoliation
- 3.3.9.2 Functionalization
- 3.3.10 Interpenetrating Polymer Networks
- 3.3.10.1 Curing Kinetics
- 3.3.10.2 Unsaturated Polyesters
- 3.3.10.3 Acrylics
- 3.3.10.4 Urethane-Modi ed Bismaleimide
- 3.3.10.5 Poly(caprolactone) and Poly(urethane)
- 3.3.10.6 Electrically Conductive Networks
- 3.3.11 Organic and Inorganic Hybrids
- 3.3.12 Flame Retardants
- 3.3.12.1 Polyphosphazene Nanotubes
- 3.3.12.2 Polyphosphazene Nanoshells
- 3.3.12.3 Burning Behavior
- 3.3.12.4 Phosphazenes
- 3.3.12.5 Phosphonamidate-Phosphonate
- 3.3.12.6 Phosphorus-Containing Epoxy Resins
- 3.3.12.7 Phosphonic Acid Salts
- 3.3.12.8 Polysiloxane-Containing Nitrogen
- 3.3.13 Corrosion Inhibitor
- 3.3.14 Production Data
- 3.4 Curing
- 3.4.1 Initiator Systems.