Liquid chromatography. Volume 1, Fundamentals and instrumentation /

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Bibliographic Details
Other Authors Fanali, Salvatore (Editor), Haddad, Paul R. (Editor), Poole, Colin F. (Editor), Riekkola, Marja-Liisa (Editor)
Format Electronic eBook
LanguageEnglish
Published Amsterdam, Netherlands : Elsevier, [2017]
EditionSecond edition.
Subjects
Liquid chromatography.
elektronické knihy
electronic books
Online AccessFull text
ISBN9780128093450
0128093455
9780128053935
0128053933
Physical Description1 online resource.

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TOC from ObalkyKnih.cz
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245 0 0 |a Liquid chromatography.  |n Volume 1,  |p Fundamentals and instrumentation /  |c edited by Salvatore Fanali, Paul R. Haddad, Colin F. Poole, Marja-Liisa Riekkola. 
246 3 0 |a Fundamentals and instrumentation 
250 |a Second edition. 
264 1 |a Amsterdam, Netherlands :  |b Elsevier,  |c [2017] 
300 |a 1 online resource. 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
500 |a Includes index. 
505 0 |a Front Cover -- Liquid Chromatography: Fundamentals and Instrumentation -- Copyright -- Contents -- Contributors -- Chapter 1: Milestones in the development of liquid chromatography -- 1.1 Introduction -- 1.1.1 Developments Before 1960 -- 1.1.2 HPLC at the Beginning -- 1.2 HPLC Theory and Practice -- 1.2.1 New HPLC Modes and Techniques -- 1.2.2 Selection of Conditions for the Control of Selectivity -- 1.3 Columns -- 1.3.1 Particles and Column Packing -- 1.3.2 Stationary Phases and Selectivity -- 1.4 Equipment -- 1.5 Detectors -- Apologies and Acknowledgments -- References -- Further Reading -- Chapter 2: Kinetic theories of liquid chromatography -- 2.1 Introduction -- 2.2 Macroscopic Kinetic Theories -- 2.2.1 Lumped Kinetic Model -- 2.2.1.1 van Deemter plate height equation -- 2.2.2 General Rate Model -- 2.2.2.1 General rate model for monolith columns -- 2.2.2.2 General rate model for core-shell particles -- 2.2.2.3 Moment analysis -- 2.2.3 Lumped Pore Diffusion Model -- 2.2.4 Equivalence of the Macroscopic Kinetic Models -- 2.2.5 Kinetic Theory of Nonlinear Chromatography -- 2.3 Microscopic Kinetic Theories -- 2.3.1 Stochastic Model -- 2.3.1.1 Stochastic-dispersive model -- First passage time -- 2.3.2 Giddings Plate Height Equation -- 2.3.3 Monte Carlo Simulations of Nonlinear Chromatography -- 2.4 Comparison of the Microscopic and the Macroscopic Kinetic Models -- References -- Further Reading -- Chapter 3: Column technology in liquid chromatography -- 3.1 Introduction -- 3.2 Column Design and Hardware -- 3.2.1 Column History in Brief -- 3.2.2 Column Hardware -- 3.2.3 Column Miniaturization -- 3.3 Column Packing Materials and Stationary Phases -- 3.3.1 Terminology -- 3.3.2 Classification of LC Columns -- 3.3.3 Packing Materials [21] -- 3.3.3.1 Particle shape, size, and size distribution -- 3.3.3.2 Pore structure parameters. 
505 8 |a 3.3.3.3 Surface functionalization of silica-the key to gaining selectivity -- 3.3.3.4 Surface functionalization of silica-the way to bonded silica columns -- 3.3.4 Major Synthesis Routes -- 3.3.4.1 Physicochemical characterization of bonded silica -- 3.3.4.2 Column packing procedures for analytical columns -- 3.3.4.3 Examples for selective bonded silica columns -- 3.3.4.4 The potential of multimodal or multifunctional bonded columns -- 3.4 Column Systems and Operations -- 3.4.1 Choice of Average Particle Size and Column Internal Diameter -- 3.4.2 Equilibration Time -- 3.4.3 Choice of Optimum-Flow Conditions -- 3.4.4 Column Back Pressure -- 3.4.5 Choice of Column Temperature -- 3.4.6 Column Capacity and Loadability -- 3.5 Chromatographic Column Testing and Evaluation -- 3.5.1 Chromatographic Testing -- 3.5.1.1 Hydrophobicity -- 3.5.1.2 Silanophilic activity -- 3.5.1.3 Polar selectivity -- 3.5.1.4 Shape selectivity -- 3.5.1.5 Metal content -- 3.6 Column Maintenance and Troubleshooting -- 3.6.1 Silica-Based Columns -- 3.6.1.1 General guidelines -- 3.6.2 pH Stability -- 3.6.3 Mechanical Stability -- 3.6.4 Mobile Phases (Eluents) -- 3.6.4.1 Proper storage of HPLC columns -- 3.6.4.2 Regeneration of a column -- 3.6.5 Regeneration of RP Packings -- 3.6.6 Polymer-Based Columns -- 3.6.6.1 General guidelines -- 3.6.7 Hydrophobic Unmodified Polystyrene-Divinylbenzene (Ps-Dvb) -- 3.6.8 Polymer-Based Ion-Exchangers -- 3.6.9 Regeneration of Polymer Materials -- 3.7 Today's Column Market-an Evaluation, Comparison, and Critical Appraisal -- 3.7.1 Development During 2000-16 -- 3.7.2 A Column Comparison -- 3.8 Conclusion: Where Do We Go Next? Science vs. Market -- References -- Chapter 4: Reversed-phase liquid chromatography -- 4.1 Introduction -- 4.2 General Features -- 4.2.1 Solvent Strength -- 4.2.2 Exothermodynamic Relationships. 
505 8 |a 4.2.3 Thermodynamic Considerations -- 4.3 System Considerations -- 4.3.1 Interphase Model -- 4.3.2 Molecular Dynamics Simulations -- 4.4 Linear Free Energy Relationships -- 4.4.1 Solvation Parameter Model -- 4.4.1.1 Analysis of system constants -- 4.4.1.2 Pore dewetting -- 4.4.1.3 Steric resistance and shape selectivity -- 4.4.1.4 Electrostatic interactions -- 4.4.1.5 Gradient elution -- 4.4.2 Hydrophobic-Subtraction Model -- 4.5 Conclusions -- References -- Chapter 5: Secondary chemical equilibria in reversed-phase liquid chromatography -- 5.1 Introduction -- 5.2 Acid-Base Equilibria -- 5.2.1 Changes in Retention With pH -- 5.2.2 Buffers and Measurement of pH -- 5.3 Ion Interaction Chromatography -- 5.3.1 Retention Mechanism -- 5.3.2 Common Reagents and Operational Modes -- 5.3.3 Separation of Inorganic Anions -- 5.3.4 The Silanol Effect and Its Suppression With Amine Compounds -- 5.3.5 Use of Perfluorinated Carboxylate Anions and Chaotropic Ions as Additives -- 5.3.6 Use of ILs as Additives -- 5.3.7 Measurement of the Enhancement of Column Performance Using Additives -- 5.4 Micellar Liquid Chromatography -- 5.4.1 An Additional Secondary Equilibrium in the Mobile Phase -- 5.4.2 Hybrid Micellar Liquid Chromatography -- 5.4.3 Microemulsion Liquid Chromatography -- 5.5 Metal Complexation -- 5.5.1 Determination of Metal Ions -- 5.5.2 Determination of Organic Compounds -- 5.6 Use of Redox Reactions -- References -- Chapter 6: Hydrophilic interaction liquid chromatography -- 6.1 Introduction -- 6.2 Principles of HILIC -- 6.2.1 Thermodynamics of Adsorption -- 6.2.2 Adsorption Kinetics -- 6.3 Stationary and mobile phases commonly employed in HILIC -- 6.3.1 Stationary Phases -- 6.3.1.1 Silica gel -- 6.3.1.2 Chemically bonded phases -- 6.3.1.3 Ion exchange and zwitterionic stationary phase -- 6.3.1.4 Hydrophilic macromolecules bonded phases. 
505 8 |a 6.3.1.5 Surface-confined ionic liquids stationary phases -- 6.3.2 Mobile Phases -- 6.4 Applications -- References -- Chapter 7: Hydrophobic interaction chromatography* -- 7.1 Introduction -- 7.2 Hydrophobic Interactions and Retention Mechanisms in HIC -- 7.2.1 Hydrophobic Interactions -- 7.2.2 Retention Mechanisms in HIC -- 7.3 Parameters That Affect HIC -- 7.3.1 Stationary Phase -- 7.3.1.1 Base matrix -- 7.3.1.2 Ligands -- 7.3.2 Mobile Phase -- 7.3.2.1 Type and concentration of salt -- 7.3.2.2 pH -- 7.3.2.3 Additives -- 7.3.2.4 Temperature -- 7.3.3 Biomolecules Hydrophobicity -- 7.4 Purification Strategies -- 7.5 Experimental Considerations -- 7.6 Recent Selected Applications -- 7.7 Conclusions -- References -- Chapter 8: Liquid-solid chromatography -- 8.1 Introduction -- 8.2 Retention and Separation -- 8.2.1 The Retention Process ("Mechanism") -- 8.2.2 Solute and Solvent Localization -- 8.2.3 Selectivity -- 8.3 Method Development -- 8.3.1 Thin-Layer Chromatography -- 8.3.2 Selection of the Mobile Phase -- 8.3.3 Example of Method Development -- 8.4 Problems in the Use of Normal-Phase Chromatography -- References -- Further Reading -- Chapter 9: Ion chromatography -- 9.1 Introduction -- 9.1.1 Definitions -- 9.1.2 History -- 9.2 Basic Principles and Separation Modes -- 9.2.1 Ion-Exchange Chromatography -- 9.2.2 Ion-Exclusion Chromatography -- 9.2.3 Chelation Ion Chromatography -- 9.2.4 Zwitterionic Ion Chromatography -- 9.2.5 Eluents for IC -- 9.2.5.1 Typical eluents for anion exchange -- 9.2.5.2 Typical eluents for cation exchange -- 9.3 Instrumentation -- 9.3.1 IC Columns -- 9.3.1.1 Anion-exchange columns -- 9.3.1.2 Cation-exchange columns -- 9.3.2 Eluent Generators -- 9.3.3 Detection in IC -- 9.3.3.1 Conductimetric detection -- Nonsuppressed conductivity -- Suppressed conductivity -- 9.3.3.2 Electrochemical detection -- Charge detector. 
505 8 |a Amperometry -- 9.3.3.3 Spectroscopic detection -- Photometric detection -- Postcolumn reaction detection -- 9.3.3.4 Mass spectrometry -- 9.4 Applications -- 9.4.1 Industrial Applications -- 9.4.2 Environmental Applications -- References -- Further Reading -- Chapter 10: Size-exclusion chromatography -- 10.1 Introduction -- 10.2 Historical Background -- 10.3 Retention in SEC -- 10.3.1 A Size-Exclusion Process -- 10.3.2 An Entropy-Controlled Process -- 10.3.3 An Equilibrium Process -- 10.4 Band Broadening in SEC -- 10.4.1 Extra-column effects -- 10.5 Resolution in SEC -- 10.6 SEC Enters the Modern Era: The Determination of Absolute Molar Mass -- 10.6.1 Universal Calibration and Online Viscometry -- 10.6.2 SLS Detection -- 10.7 Multidetector Separations, Physicochemical Characterization, 2D Techniques -- 10.8 Conclusions -- Acknowledgment and Disclaimer -- References -- Chapter 11: Interaction polymer chromatography -- 11.1 Introduction -- 11.2 Fundamentals of ipc -- 11.2.1 Retention Mechanisms -- 11.2.2 Thermodynamics of Polymer Chromatography -- 11.2.3 Modes of Polymer Chromatography -- 11.2.4 Modeling of the Chromatographic Process -- 11.3 Individual IPC Techniques -- 11.3.1 Equipment and Chromatographic Media -- 11.3.2 Nomenclature -- 11.3.3 Isocratic Techniques -- 11.3.3.1 Liquid chromatography at critical conditions -- 11.3.3.2 Barrier techniques -- 11.3.4 Gradient Techniques -- 11.3.4.1 Liquid adsorption chromatography -- 11.3.4.2 Gradient elution at CPA -- 11.3.4.3 Liquid precipitation chromatography -- 11.3.4.4 Temperature gradient interaction chromatography -- 11.4 Conclusion -- References -- Chapter 12: Affinity chromatography -- 12.1 Introduction -- 12.2 Basic Components of Affinity Chromatography -- 12.3 Bioaffinity Chromatography -- 12.4 Immunoaffinity Chromatography -- 12.5 Dye-Ligand and Biomimetic Affinity Chromatography. 
506 |a Plný text je dostupný pouze z IP adres počítačů Univerzity Tomáše Bati ve Zlíně nebo vzdáleným přístupem pro zaměstnance a studenty 
590 |a Knovel  |b Knovel (All titles) 
650 0 |a Liquid chromatography. 
655 7 |a elektronické knihy  |7 fd186907  |2 czenas 
655 9 |a electronic books  |2 eczenas 
700 1 |a Fanali, Salvatore,  |e editor.  |1 https://id.oclc.org/worldcat/entity/E39PBJkHhWDYbfwxmcMmGyj9jC 
700 1 |a Haddad, Paul R.,  |e editor.  |1 https://id.oclc.org/worldcat/entity/E39PBJdCqTr6Mggdq6bJp46dwC 
700 1 |a Poole, Colin F.,  |e editor. 
700 1 |a Riekkola, Marja-Liisa,  |e editor. 
776 0 8 |i Print version:  |z 0128053933  |z 9780128053935  |w (OCoLC)964303423 
856 4 0 |u https://proxy.k.utb.cz/login?url=https://app.knovel.com/hotlink/toc/id:kpLCFIVE01/liquid-chromatography-fundamentals?kpromoter=marc  |y Full text 

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