Porous polymers : design, synthesis and applications

• Main Authors: Qiu, Shilun (Author), Teng, Ben (Author)
• Format: Electronic eBook
• Language: English
• Published: Cambridge, UK : Royal Society of Chemistry, [2016]
• Series: Monographs in supramolecular chemistry ; no. 17.
• Subjects: Porous materials.; Polymers.; elektronické knihy; electronic books
• ISBN: 9781782622260; 1782622268; 9781523101955; 1523101954; 1849739323; 9781849739320
• Physical Description: 1 online resource (xi, 311 pages .)

Porous materials with ultrahigh surface area are of great interest for potential applications in energy storage and environmental remediation. Porous Polymers describes the significant recent progress in the development of different porous frameworks, with a particular focus on the relationship betw...

Table of Contents:

• Cover; Contents; Preface; Chapter 1 Introduction; References; Chapter 2 Design Principle of Porous Polymers; 2.1 Design Principle of Porous Polymers; 2.2 Theoretical Simulation; 2.3 Pore Size Tailoring; 2.4 Framework Modification; 2.5 Carbonization; 2.6 Interpenetration Control and Utilization; 2.7 Structural Order and Disorder; References; Chapter 3 Chemical Synthesis of Porous Polymers; 3.1 Introduction; 3.2 Amorphous Porous Polymers; 3.2.1 Insoluble Porous Polymers; 3.2.2 Soluble Porous Polymers; 3.3 Crystalline Covalent Organic Frameworks; 3.4 Emerging Porous Organic Materials.
• 3.4.1 Porous Organic Cages3.4.2 Mastalerz Compounds; References; Chapter 4 Recent Developments of Hypercrosslinked Microporous Organic Polymers; 4.1 Short Overview of Microporous Materials; 4.2 Synthetic Strategy to Hypercrosslinked Polymers; 4.2.1 Post-crosslinking Procedure; 4.2.2 Direct One-step Self-polycondensation; 4.2.3 External Crosslinking Strategy; 4.3 Conclusion and Outlook; Acknowledgments; References; Chapter 5 Polymers of Instrinsic Microporosity; 5.1 Introduction; 5.2 Design and Synthesis of PIMs; 5.3 Structure of PIMs; 5.4 Porosity of PIMs.
• 5.4.1 Understanding the Porosity of Porous Polymers5.5 Applications; 5.5.1 Gas Permeation Studies; 5.5.2 Storage; 5.5.3 Catalysis; 5.5.4 Adsorption of Organic Compounds; References; Chapter 6 Rational Design of Covalent Organic Frameworks for High Performance Gas Storage; 6.1 Introduction; 6.2 Theoretical Methods; 6.2.1 Quantum Chemistry; 6.2.2 Molecular Simulations; 6.2.3 Multiscale Simulation; 6.3 Building Blocks Utilized for COF Materials; 6.4 Strategies for the Design of New COF Materials; 6.4.1 Linker Replacement Strategy; 6.4.2 Node Replacement Strategy; 6.4.3 Functionalization Strategy.
• 6.5 Applications6.5.1 Hydrogen Storage; 6.5.2 Methane Storage; 6.5.3 Carbon Dioxide Storage; 6.5.4 Ammonia Storage; 6.6 Summary and Perspectives; Acknowledgments; References; Chapter 7 Conjugated Microporous Polymers; 7.1 Introduction; 7.2 Synthesis; 7.3 Structure; 7.3.1 Basic Structure; 7.3.2 Structural Order; 7.3.3 Structural Packing; 7.4 Structure and Porosity Analysis; 7.4.1 Structure Analysis; 7.4.2 Porosity Analysis; 7.5 Structure Control and Functionality; 7.5.1 Structure Control; 7.5.2 Synthetic Conditions; 7.5.3 Chemical Functionality; 7.5.4 Electronic and Optical Properties.
• 7.6 Applications7.7 Limitations; 7.8 Future Directions; 7.9 Summary; References; Chapter 8 Porous Aromatic Frameworks; 8.1 Introduction; 8.2 Synthesis of Porous Aromatic Frameworks; 8.2.1 Yamamoto-type Ullmann Cross-coupling Reaction; 8.2.2 Suzuki Coupling Reaction; 8.2.3 Ionothermal Reaction; 8.2.4 Friedel-Crafts Alkylation Reaction; 8.2.5 Summary; 8.3 Properties and Applications of Porous Aromatic Frameworks; 8.3.1 Gas Sorption and Separation; 8.3.2 Adsorption of Organic Pollutants; 8.3.3 Electroactive and Battery Applications; 8.3.4 Summary; 8.4 Theoretical Simulation and Calculation.