Advanced practical organic chemistry.

• Main Authors: Leonard, J. 1954- (Author), Lygo, B., (Author), Procter, Garry, (Author)
• Format: eBook
• Language: English
• Published: Boca Raton : CRC Press, Taylor & Francis Group, [2013]
• Edition: Third edition /
• Subjects: Organic compounds > Synthesis.; Chemistry, Organic > Laboratory manuals.; elektronické knihy; electronic books
• ISBN: 9781628706864; 1628706864; 9781466593541; 1466593547; 9781466593558; 1466593555; 9781439860984; 143986098X; 9781439860977; 1439860971
• Physical Description: 1 online resource (xxv, 330 pages) : illustrations
• Access: Plný text je dostupný pouze z IP adres počítačů Univerzity Tomáše Bati ve Zlíně nebo vzdáleným přístupem pro zaměstnance a studenty

General introductionSafetySafety is your primary responsibilitySafe working practiceSafety risk assessmentsCommon hazardsAccident and emergency proceduresBibliographyKeeping records of laboratory workIntroductionThe laboratory notebookKeeping records of dataSome tips on report and thesis preparationReferencesEquipping the laboratory and the benchIntroductionSetting up the laboratoryGeneral laboratory equipmentThe individual benchEquipment for parallel experimentsEquipment for controlled experimentationPurification and drying of solventsIntroductionPurification of solventsDrying agentsDrying of solventsReferencesReagents: Preparation, purification, and handlingIntroductionClassification of reagents for handlingTechniques for obtaining pure and dry reagentsTechniques for handling and measuring reagentsPreparation and titration of simple organometallic reagents and lithium amide basesPreparation of diazomethaneReferencesGasesIntroductionUse of gas cylindersHandling gasesMeasurement of gasesInert gasesReagent gasesReferencesVacuum pumpsIntroductionHouse vacuum systems (low vacuum)Medium vacuum pumpsHigh vacuum pumpsPressure measurement and regulationCarrying out the reactionIntroductionReactions with air-sensitive reagentsReaction monitoringReactions at other than room temperatureDriving equilibriaAgitationUse of controlled reactor systemsReferencesWorking up the reactionIntroductionQuenching the reactionIsolation of the crude productData that need to be collected on the crude product prior to purificationPurificationIntroductionCrystallizationDistillationSublimationFlash chromatographyDry-column flash chromatographyPreparative TLCMedium pressure and prepacked chromatography systemsPreparative HPLCReferencesSmall-scale reactionsIntroductionReactions at or below room temperatureReactions above room temperatureReactions in NMR tubesPurification of.
MaterialsLarge-scale reactionsIntroductionCarrying out the reactionWorkup and product isolationPurification of the productsSpecial proceduresIntroductionCatalytic hydrogenationPhotolysisOzonolysisFlash vacuum pyrolysis (FVP)Liquid ammonia reactionsMicrowave reactionsReferencesCharacterizationIntroductionNMR spectraIR spectraUV spectroscopyMass spectrometryMelting point (m.p.) and boiling point (b.p.)Optical rotationMicroanalysisKeeping the dataTroubleshooting: What to do when things don't workThe chemical literatureThe structure of the chemical literatureSome important paper-based sources of chemical informationSome important electronic-based sources of chemical informationHow to find chemical informationCurrent awarenessReferencesAppendicesProperties of common solventsProperties of common gasesApproximate pKa values for some common reagents versus common basesCommon Bronsted acidsCommon Lewis acidsCommon reducing reagentsCommon oxidizing reagentsIndex.