Battery systems engineering

A complete all-in-one reference on the important interdisciplinary topic of Battery Systems Engineering Focusing on the interdisciplinary area of battery systems engineering, this book provides the background, models, solution techniques, and systems theory that are necessary for the development of...

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Bibliographic Details
Main Author Rahn, Christopher D.
Format Electronic eBook
LanguageEnglish
Published Hoboken : Wiley, 2013.
Subjects
Online AccessFull text
ISBN9781118517055
1118517059
9781118517031
1118517032
9781118517062
1118517067
9781118517048
1118517040
9781523110070
1523110074
9781119979500
1119979501
1299188257
9781299188259
Physical Description1 online resource

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Table of Contents:
  • 1 Introduction; 1.1 Energy Storage Applications; 1.2 The Role of Batteries; 1.3 Battery Systems Engineering; 1.4 A Model-Based Approach; 1.5 Electrochemical Fundamentals; 1.6 Battery Design; 1.7 Objectives of this Book; 2 Electrochemistry; 2.1 Lead-Acid; 2.2 Nickel-Metal Hydride; 2.3 Lithium-Ion; 2.4 Performance Comparison; 2.4.1 Energy Density and Specific Energy; 2.4.2 Charge and Discharge; 2.4.3 Cycle Life; 2.4.4 Temperature Operating Range; 3 Governing Equations; 3.1 Thermodynamics and Faraday's Law; 3.2 Electrode Kinetics.
  • 3.2.1 The Butler-Volmer Equation3.2.2 Double-Layer Capacitance; 3.3 Solid Phase of Porous Electrodes; 3.3.1 Intercalate Species Transport; 3.3.2 Conservation of Charge; 3.4 Electrolyte Phase of Porous Electrodes; 3.4.1 Ion Transport; 3.4.2 Conservation of Charge; 3.4.3 Concentrated Solution Theory; 3.5 Cell Voltage; 3.6 Cell Temperature; 3.6.1 Arrhenius Equation; 3.6.2 Conservation of Energy; 3.7 Side Reactions and Aging; Problems; 4 Discretization Methods; 4.1 Analytical Method; 4.1.1 Electrolyte Diffusion; 4.1.2 Coupled Electrolyte-Solid Diffusion in Pb Electrodes.
  • 4.1.3 Solid-State Diffusion in Li-Ion and Ni-MH Particles 4.2 Pad Approximation Method; 4.2.1 Solid-State Diffusion in Li-Ion Particles; 4.3 Integral Method Approximation; 4.3.1 Electrolyte Diffusion; 4.3.2 Solid-State Diffusion in Li-Ion and Ni-MH Particles; 4.4 Ritz Method; 4.4.1 Electrolyte Diffusion in a Single Domain; 4.4.2 Electrolyte Diffusion in Coupled Domains; 4.4.3 Coupled Electrolyte-Solid Diffusion in Pb Electrodes; 4.5 Finite-Element Method; 4.5.1 Electrolyte Diffusion; 4.5.2 Coupled Electrolyte-Solid Diffusion in Li-Ion Electrodes.
  • 4.6 Finite-Difference Method; 4.6.1 Electrolyte Diffusion4.6.2 Nonlinear Coupled Electrolyte-Solid Diffusion in Pb Electrodes; 4.7 System Identification in the Frequency Domain; 4.7.1 System Model; 4.7.2 Least-Squares Optimization Problem; 4.7.3 Optimization Approach; 4.7.4 Multiple Outputs; 4.7.5 System Identification Toolbox; 4.7.6 Experimental Data; Problems; 5 System Response; 5.1 Time Response; 5.1.1 Constant Charge/Discharge Current; 5.1.2 DST Cycle Response of the Pb-Acid Electrode; 5.2 Frequency Response; 5.2.1 Electrochemical Impedance Spectroscopy; 5.2.2 Discretization Efficiency; 5.3 Model Order Reduction.
  • 5.3.1 Truncation Approach5.3.2 Grouping Approach; 5.3.3 Frequency-Response Curve Fitting; 5.3.4 Performance Comparison; Problems; 6 Battery System Models; 6.1 Lead-Acid Battery Model; 6.1.1 Governing Equations; 6.1.2 Discretization using the Ritz Method; 6.1.3 Numerical Convergence; 6.1.4 Simulation Results; 6.2 Lithium-Ion Battery Model; 6.2.1 Conservation of Species; 6.2.2 Conservation of Charge; 6.2.3 Reaction Kinetics; 6.2.4 Cell Voltage; 6.2.5 Linearization; 6.2.6 Impedance Solution; 6.2.7 FEM Electrolyte Diffusion; 6.2.8 Overall System Transfer Function.