Reaction mechanisms of metal complexes
Annotation
Saved in:
| Main Author | |
|---|---|
| Format | Electronic eBook |
| Language | English |
| Published |
Chichester :
Horwood,
2000.
|
| Series | Horwood chemical science series.
|
| Subjects | |
| Online Access | Full text |
| ISBN | 9781613448137 1613448139 9781782420637 1782420630 1898563411 9781898563419 |
| Physical Description | 1 online resource (170 pages) : illustrations |
Cover
Table of Contents:
- The two Reaction PathwaysThe Intimate Mechanism; The Trans Effect; Activation Parameters; Reaction Pathways from Structural Data; Cis-Effects; The Central Metal Ion; The Dissociative Pathway; Five Coordinate Complexes; Theoretical Calculations; The Application of Reaction Mechanisms to Synthesis; Carboplatin; Reactivity Patterns; Bibliography and References; Chapter 5. Isomerisation and Racemisation Reactions; Introduction; Stereochemical Topics; Absolute Configurations; Optical Rotatory Dispersion; Kinetic Data; Spectrophotometric Method; Polarimetric methods; N.m.r. Techniques.
- Mechanisms of Isomerisation and RacemisationTopological Mechanisms; Berry Pseudorotation; The Bailar Twist; Inversion and Proton Exchange at Asymmetric Nitrogen Centres; Bibliography and References; Chapter 6. Electron Transfer Reactions; Introduction; Outer Sphere Reactions; The Theory of Outer Sphere Redox Reactions; The Marcus Equation; The Inner Sphere Mechanism; The Precursor Complex; Electronic Considerations; Activation Parameters; Long Range Electron Transfer in Metalloproteins; Optical Charge Transfer; Stereoselective Electron Transfer; Intramolecular Electron Transfer.