Reaction mechanisms of metal complexes

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Bibliographic Details
Main Author: Hay, R. W. 1934-
Format: eBook
Language: English
Published: Chichester : Horwood, 2000.
Series: Horwood chemical science series.
Subjects:
ISBN: 9781613448137
1613448139
9781782420637
1782420630
1898563411
9781898563419
Physical Description: 1 online resource (170 pages) : illustrations

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042 |a dlr 
100 1 |a Hay, R. W.  |q (Robert Walker),  |d 1934-  |1 https://id.oclc.org/worldcat/entity/E39PCjrmPQT8Htp7bMjJdVrbbd 
245 1 0 |a Reaction mechanisms of metal complexes /  |c Robert W. Hay. 
260 |a Chichester :  |b Horwood,  |c 2000. 
300 |a 1 online resource (170 pages) :  |b illustrations 
336 |a text  |b txt  |2 rdacontent 
337 |a computer  |b c  |2 rdamedia 
338 |a online resource  |b cr  |2 rdacarrier 
490 1 |a Horwood chemical science series 
506 |a Plný text je dostupný pouze z IP adres počítačů Univerzity Tomáše Bati ve Zlíně nebo vzdáleným přístupem pro zaměstnance a studenty 
520 8 |a Annotation  |b This text provides a general background as a course module in the area of inorganic reaction mechanisms, suitable for advanced undergraduate and postgraduate study and/or research. The topic has important research applications in the metallurgical industry and is of interest in the science of biochemistry, biology, organic, inorganic and bioinorganic chemistry. In addition to coverage of substitution reactions in four-, five- and six-coordinate complexes, the book contains further chapters devoted to isomerization and racemization reactions, to the general field of redox reactions, and to the reactions of coordinated ligands. It is relevant in other fields such as organic, bioinorganic and biological chemistry, providing a bridge to organic reaction mechanisms. The book also contains a chapter on the kinetic background to the subject with many illustrative examples which should prove useful to those beginning research. 
504 |a Includes bibliographical references and index. 
505 8 |a The two Reaction PathwaysThe Intimate Mechanism; The Trans Effect; Activation Parameters; Reaction Pathways from Structural Data; Cis-Effects; The Central Metal Ion; The Dissociative Pathway; Five Coordinate Complexes; Theoretical Calculations; The Application of Reaction Mechanisms to Synthesis; Carboplatin; Reactivity Patterns; Bibliography and References; Chapter 5. Isomerisation and Racemisation Reactions; Introduction; Stereochemical Topics; Absolute Configurations; Optical Rotatory Dispersion; Kinetic Data; Spectrophotometric Method; Polarimetric methods; N.m.r. Techniques. 
505 8 |a Mechanisms of Isomerisation and RacemisationTopological Mechanisms; Berry Pseudorotation; The Bailar Twist; Inversion and Proton Exchange at Asymmetric Nitrogen Centres; Bibliography and References; Chapter 6. Electron Transfer Reactions; Introduction; Outer Sphere Reactions; The Theory of Outer Sphere Redox Reactions; The Marcus Equation; The Inner Sphere Mechanism; The Precursor Complex; Electronic Considerations; Activation Parameters; Long Range Electron Transfer in Metalloproteins; Optical Charge Transfer; Stereoselective Electron Transfer; Intramolecular Electron Transfer. 
590 |a Knovel  |b Knovel (All titles) 
650 0 |a Metal complexes. 
650 0 |a Reaction mechanisms (Chemistry) 
655 7 |a elektronické knihy  |7 fd186907  |2 czenas 
655 9 |a electronic books  |2 eczenas 
776 0 8 |i Print version:  |a Hay, R.W. (Robert W).  |t Reaction mechanisms of metal complexes.  |d Chichester : Horwood, 2000  |w (OCoLC)43880472 
830 0 |a Horwood chemical science series. 
856 4 0 |u https://proxy.k.utb.cz/login?url=https://app.knovel.com/hotlink/toc/id:kpRMMC0005/reaction-mechanisms-of?kpromoter=marc  |y Full text