Engineering catalysis

With well over 90% of all processes in the industrial chemical production being of catalytic nature, catalysis is a mature though ever interesting topic. The idea of this book is to tackle various aspects of heterogeneous catalysis from the engineering point of view and go all the way from engineeri...

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Bibliographic Details
Main Author: Murzin, Dmitry.
Format: eBook
Language: English
Published: Berlin : De Gruyter, 2013.
Series: De Gruyter textbook.
Subjects:
Catalysis > Industrial applications.
Chemical reactors.
Chemical engineering.
elektronické knihy
electronic books
ISBN: 9783110283372
9783110283365
Physical Description: 1 online zdroj (376 pages).

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Table of contents

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020 |a 9783110283372  |q (ebook) 
020 |a 9783110283365 
035 |a (OCoLC)858761768 
040 |a EBLCP  |b eng  |e pn  |c EBLCP  |d OCLCO  |d OCLCQ  |d E7B  |d N$T  |d KNOVL  |d OCLCQ  |d TR7RH  |d COO  |d ZCU 
100 1 |a Murzin, Dmitry. 
245 1 0 |a Engineering catalysis  |h [elektronický zdroj] /  |c Dmitry Yu. Murzin. 
260 |a Berlin :  |b De Gruyter,  |c 2013. 
300 |a 1 online zdroj (376 pages). 
336 |a text  |b txt  |2 rdacontent 
337 |a počítač  |b c  |2 rdamedia 
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490 1 |a De Gruyter textbook 
520 |a With well over 90% of all processes in the industrial chemical production being of catalytic nature, catalysis is a mature though ever interesting topic. The idea of this book is to tackle various aspects of heterogeneous catalysis from the engineering point of view and go all the way from engineering of catalysis, catalyst preparation, characterization, reaction kinetics, mass transfer to catalytic reactors and the implementation of catalysts in chemical technology. Aimed for graduate students it is also a useful resource for professionals coming from the more academic side. 
505 0 |a Preface; 1 The basics; 1.1 Catalytic concepts; 1.1.1 Definitions; 1.1.2 Length and time scales in catalysis; 1.1.3 Catalytic trinity: activity, selectivity, stability; 1.1.4 Composition of catalysts; 1.2 Reactivity of solids; 1.2.1 Physisorption and chemisorption; 1.2.2 Basics of chemisorption theory; 1.2.3 Surface crystallography; 1.2.4 Mechanisms of some catalytic reactions; 1.3 Catalysis in industry; References; 2 Engineering catalysts; 2.1 Catalyst design; 2.1.1 Being in shape; 2.1.2 Scaling of catalysts; 2.2 Toolbox in catalysis; 2.2.1 General overview of the characterization methods. 
505 8 |a 2.2.2 Adsorption methods2.2.3 Physisorption methods; 2.2.4 Chemisorption; 2.2.5 Temperature-programmed methods; 2.2.6 Calorimetry; 2.2.7 X-ray diffraction; 2.2.8 X-ray photoelectron spectroscopy and X-ray fluorescence; 2.2.9 Infrared and Raman spectroscopies; 2.2.10 Catalyst particle size measurements; 2.2.11 Electron paramagnetic/spin resonance; 2.2.12 Mössbauer spectroscopy; 2.2.13 X-ray absorption spectroscopy; 2.2.14 Nuclear magnetic resonance; 2.2.15 Imaging of catalysts; 2.2.16 Catalytic reactions: product analysis; 2.2.17 Theory as a part of a toolbox. 
505 8 |a 2.3 Preparation of catalytic materials2.3.1 General overview; 2.3.2 Unsupported metals; 2.3.3 Preparation of bulk oxides by precipitation; 2.3.4 Heteropolyacids; 2.3.5 Catalysts supports; 2.3.6 Supported catalysts; 2.3.7 Catalyst forming operations; References; 3 Engineering reactions; 3.1 Introduction; 3.2 Thermodynamics; 3.3 Kinetics; 3.3.1 Definitions; 3.3.2 Reaction mechanism; 3.3.3 Kinetics of complex reactions; 3.3.4 Relationship between thermodynamics and kinetics; 3.3.5 Non-ideal surfaces; 3.4 Kinetic aspects of selectivity; 3.4.1 Structure sensitivity. 
505 8 |a 3.4.2 Mechanism-free kinetics -- kinetic polynomial3.4.3 What is behind a rate constant?; 3.4.4 Dynamic catalysis; 3.4.5 Deactivation; 3.4.6 Mathematical treatment of experimental data; 3.5 Mass transfer; 3.5.1 Diffusion effects in heterogeneous catalysis; 3.5.2 Reactor dependent external diffusion (interphase mass transfer, film diffusion); 3.5.3 Calculation of diffusion coefficients; 3.5.4 Size dependent internal (pore) diffusion; 3.5.5 Non-isothermal conditions; 3.5.6 Multiple reactions and diffusional limitations; 3.5.7 Diffusion in micropores. 
505 8 |a 3.5.8 Criteria for the absence of diffusional limitations3.6 Catalytic reactors; 3.6.1 Laboratory reactors; 3.6.2 Industrial reactors; 3.6.3 Two-phase reactors; 3.6.4 Three-phase catalytic reactors; 3.6.5 Reactor modeling; 3.6.6 Catalyst handing in a plant; References; 4 Engineering technology; 4.1 General structures of chemical processes; 4.1.1 Safety in design; 4.1.2 Conceptual process design: examples; 4.1.3 Conceptual process design: general comments; 4.1.4 Reactor selection; 4.2 (Petro)chemical industry; 4.3 Fluid catalytic cracking; 4.3.1 Feedstock; 4.3.2 Reactions/mechanism. 
504 |a Includes bibliographies and index. 
590 |a Knovel Library  |b ACADEMIC - Chemistry & Chemical Engineering 
506 |a Plný text je dostupný pouze z IP adres počítačů Univerzity Tomáše Bati ve Zlíně nebo vzdáleným přístupem pro zaměstnance a studenty univerzity 
650 0 |a Catalysis  |x Industrial applications. 
650 0 |a Chemical reactors. 
650 0 |a Chemical engineering. 
655 7 |a elektronické knihy  |7 fd186907  |2 czenas 
655 9 |a electronic books  |2 eczenas 
776 0 8 |i Print version:  |a Murzin, Dmitry.  |t Engineering Catalysis.  |d Berlin : De Gruyter, ©2013  |z 9783110283365 
830 0 |a De Gruyter textbook. 
856 4 0 |u https://proxy.k.utb.cz/login?url=http://app.knovel.com/hotlink/toc/id:kpEC000012/engineering_catalysis  |y Plný text 
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