On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes
This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current...
Saved in:
| Main Author | |
|---|---|
| Corporate Author | |
| Format | Electronic eBook |
| Language | English |
| Published |
Cham :
Springer International Publishing : Imprint: Springer,
2017.
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| Series | Springer Theses, Recognizing Outstanding Ph.D. Research,
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| Subjects | |
| Online Access | Full text |
| ISBN | 9783319518077 |
| ISSN | 2190-5053 |
| DOI | 10.1007/978-3-319-51807-7 |
| Physical Description | 1 online resource (XIX, 243 p. 170 illus., 59 illus. in color.) |
Cover
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| 100 | 1 | |a Hadlington, Terrance John. |e author. | |
| 245 | 1 | 0 | |a On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes / |c by Terrance John Hadlington. |
| 264 | 1 | |a Cham : |b Springer International Publishing : |b Imprint: Springer, |c 2017. | |
| 300 | |a 1 online resource (XIX, 243 p. 170 illus., 59 illus. in color.) | ||
| 336 | |a text |b txt |2 rdacontent | ||
| 337 | |a počítač |b c |2 rdamedia | ||
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| 490 | 1 | |a Springer Theses, Recognizing Outstanding Ph.D. Research, |x 2190-5053 | |
| 505 | 0 | |a General Introduction -- The Development of Extremely Bulky Amide Ligands and their Application to the Synthesis of Group 14 Element(II) Halides -- Synthesis and Reactivity of Heavier Alkyne Analogues Stabilised by Extremely Bulky Amide Ligands -- Reactivity of Low-Coordinate Group 14 Element(II) Hydride Complexes -- Stoichiometric Reactivity and Catalytic Applications of Heavier Tetrelene Derivatives -- The Use of a Bulky Boryl-Substituted Amide Ligand in Low-Oxidation State Group 14 Element Chemistry. | |
| 506 | |a Plný text je dostupný pouze z IP adres počítačů Univerzity Tomáše Bati ve Zlíně nebo vzdáleným přístupem pro zaměstnance a studenty | ||
| 520 | |a This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal-metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry. | ||
| 650 | 0 | |a Chemistry. | |
| 650 | 0 | |a Inorganic chemistry. | |
| 650 | 0 | |a Organometallic chemistry. | |
| 650 | 0 | |a Catalysis. | |
| 655 | 7 | |a elektronické knihy |7 fd186907 |2 czenas | |
| 655 | 9 | |a electronic books |2 eczenas | |
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| 776 | 0 | 8 | |i Printed edition: |z 9783319518060 |
| 830 | 0 | |a Springer Theses, Recognizing Outstanding Ph.D. Research, |x 2190-5053 | |
| 856 | 4 | 0 | |u https://proxy.k.utb.cz/login?url=http://dx.doi.org/10.1007/978-3-319-51807-7 |
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