On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes

This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current...

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Bibliographic Details
Main Author: Hadlington, Terrance John. (Author)
Corporate Author: SpringerLink (Online service)
Format: eBook
Language: English
Published: Cham : Springer International Publishing : Imprint: Springer, 2017.
Series: Springer Theses, Recognizing Outstanding Ph.D. Research,
Subjects:
Chemistry.
Inorganic chemistry.
Organometallic chemistry.
Catalysis.
elektronické knihy
electronic books
ISBN: 9783319518077
Physical Description: 1 online resource (XIX, 243 p. 170 illus., 59 illus. in color.)

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Table of contents

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001 100568
003 CZ-ZlUTB
005 20240914112848.0
006 m o d
007 cr nn 008mamaa
008 170214s2017 gw | s |||| 0|eng d
020 |a 9783319518077 
024 7 |a 10.1007/978-3-319-51807-7  |2 doi 
100 1 |a Hadlington, Terrance John.  |e author. 
245 1 0 |a On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes /  |c by Terrance John Hadlington. 
264 1 |a Cham :  |b Springer International Publishing :  |b Imprint: Springer,  |c 2017. 
300 |a 1 online resource (XIX, 243 p. 170 illus., 59 illus. in color.) 
336 |a text  |b txt  |2 rdacontent 
337 |a počítač  |b c  |2 rdamedia 
338 |a online zdroj  |b cr  |2 rdacarrier 
490 1 |a Springer Theses, Recognizing Outstanding Ph.D. Research,  |x 2190-5053 
505 0 |a General Introduction -- The Development of Extremely Bulky Amide Ligands and their Application to the Synthesis of Group 14 Element(II) Halides -- Synthesis and Reactivity of Heavier Alkyne Analogues Stabilised by Extremely Bulky Amide Ligands -- Reactivity of Low-Coordinate Group 14 Element(II) Hydride Complexes -- Stoichiometric Reactivity and Catalytic Applications of Heavier Tetrelene Derivatives -- The Use of a Bulky Boryl-Substituted Amide Ligand in Low-Oxidation State Group 14 Element Chemistry. 
506 |a Plný text je dostupný pouze z IP adres počítačů Univerzity Tomáše Bati ve Zlíně nebo vzdáleným přístupem pro zaměstnance a studenty 
520 |a This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal-metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry. 
650 0 |a Chemistry. 
650 0 |a Inorganic chemistry. 
650 0 |a Organometallic chemistry. 
650 0 |a Catalysis. 
655 7 |a elektronické knihy  |7 fd186907  |2 czenas 
655 9 |a electronic books  |2 eczenas 
710 2 |a SpringerLink (Online service) 
776 0 8 |i Printed edition:  |z 9783319518060 
830 0 |a Springer Theses, Recognizing Outstanding Ph.D. Research,  |x 2190-5053 
856 4 0 |u https://proxy.k.utb.cz/login?url=http://dx.doi.org/10.1007/978-3-319-51807-7  |y Plný text 
992 |c NTK-SpringerCHEMS 
999 |c 100568  |d 100568 
993 |x NEPOSILAT  |y EIZ 

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