On the Catalytic Efficacy of Low-Oxidation State Group 14 Complexes
This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current...
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| Main Author | |
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| Format | Electronic eBook |
| Language | English |
| Published |
Cham :
Springer International Publishing : Imprint: Springer,
2017.
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| Series | Springer Theses, Recognizing Outstanding Ph.D. Research,
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| Subjects | |
| Online Access | Full text |
| ISBN | 9783319518077 |
| ISSN | 2190-5053 |
| DOI | 10.1007/978-3-319-51807-7 |
| Physical Description | 1 online resource (XIX, 243 p. 170 illus., 59 illus. in color.) |
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| Summary: | This outstanding thesis describes a detailed investigation into the use of low-oxidation-state group 14 complexes in catalysis, developed at the cutting edge of inorganic and organometallic chemistry. It includes the preparation of a number of landmark compounds, some of which challenge our current understanding of metal-metal bonding and low-oxidation-state main group chemistry. Among the many highlights of this thesis, the standout result is the development of the first well-defined, low- oxidation-state main group hydride systems as highly efficient catalysts in the hydroboration of carbonyl substrates, including carbon dioxide, which are as efficient as those observed in more traditional, transition-metal catalyses. These results essentially define a new subdiscipline of chemistry. |
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| ISBN: | 9783319518077 |
| ISSN: | 2190-5053 |
| Access: | Plný text je dostupný pouze z IP adres počítačů Univerzity Tomáše Bati ve Zlíně nebo vzdáleným přístupem pro zaměstnance a studenty |
| DOI: | 10.1007/978-3-319-51807-7 |
| Physical Description: | 1 online resource (XIX, 243 p. 170 illus., 59 illus. in color.) |