Reactivity of Nitric Oxide on Copper Surfaces : Elucidated by Direct Observation of Valence Orbitals

This book provides microscopic insights into chemical properties of NO on metal surfaces. NO/metal systems have been studied intensively to understand heterogeneous catalysis to detox exhaust NOx gas. The identification and componential analysis of various and mixed chemical species of NO adsorbed o...

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Bibliographic Details
Main Author Shiotari, Akitoshi (Author)
Corporate Author SpringerLink (Online service)
Format Electronic eBook
LanguageEnglish
Published Singapore : Springer Singapore : Imprint: Springer, 2017.
SeriesSpringer Theses, Recognizing Outstanding Ph.D. Research,
Subjects
Chemistry.
Spectroscopy.
Physical chemistry.
Catalysis.
Surfaces (Physics).
Interfaces (Physical sciences).
Thin films.
Nanotechnology.
elektronické knihy
electronic books
Online AccessFull text
ISBN9789811045820
ISSN2190-5053
DOI10.1007/978-981-10-4582-0
Physical Description1 online resource (XIII, 129 p. 66 illus., 61 illus. in color.)

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Table of Contents:
  • Introduction
  • Principles and methods
  • Visualization of covalent bonding between NO molecules on Cu(110)
  • NO reduction by co-adsorbed water molecules on Cu(110)
  • Thermal and electron-induced configuration changes of NO on Cu(110)
  • Valence orbitals of high symmetry NO on Cu(001)
  • Symmetry correlation between molecular vibrations and valence orbitals: NO/Cu(110) and NO/Cu(001)
  • Formation of unique trimer of NO on Cu(111)
  • Conclusions
  • Appendix: Analysis of tunneling current modified by vibrational excitations.

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