Construction and Reactivity of Pt-Based Bi-component Catalytic Systems

In this thesis, the author outlines the construction of active structure and modulation of catalytic reactivity of Pt-based bi-component catalysts, from the model systems to real supported catalysts. The thesis investigates the promotion effect of the second components on catalytic performance of Pt...

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Bibliographic Details
Main Author Mu, Rentao (Author)
Corporate Author SpringerLink (Online service)
Format Electronic eBook
LanguageEnglish
Published Berlin, Heidelberg : Springer Berlin Heidelberg : Imprint: Springer, 2017.
SeriesSpringer Theses, Recognizing Outstanding Ph.D. Research,
Subjects
Online AccessFull text
ISBN9783662552445
ISSN2190-5053
DOI10.1007/978-3-662-55244-5
Physical Description1 online resource (XII, 90 p. 64 illus., 60 illus. in color.)

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245 1 0 |a Construction and Reactivity of Pt-Based Bi-component Catalytic Systems /  |c by Rentao Mu. 
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505 0 |a Introduction -- Experimental Methods -- Construction and Reactivity of Pt-Ni Catalysts -- Modulating the Structure and Reactivity of Pt-Ni Catalysts -- Comparison of Pt-Fe and Pt-Ni Catalysts -- Reactivity of Graphene-confined Pt(111) Surfaces -- Conclusions. 
506 |a Plný text je dostupný pouze z IP adres počítačů Univerzity Tomáše Bati ve Zlíně nebo vzdáleným přístupem pro zaměstnance a studenty 
520 |a In this thesis, the author outlines the construction of active structure and modulation of catalytic reactivity of Pt-based bi-component catalysts, from the model systems to real supported catalysts. The thesis investigates the promotion effect of the second components on catalytic performance of Pt catalysts, and presents the reversible generation of the "sandwich-like" structure of Pt-Ni catalysts, containing both surface NiO1-X and subsurface Ni by alternating redox treatments at medium temperature. With the aid of single layer graphene, the dynamic process of chemical reactions occurring on the Pt(111) surface can be visualized using in-situ LEEM and DUV-PEEM techniques, the results of which are included here. The author reveals that the graphene layer exhibits a strong confinement effect on the chemistry of molecules underneath and the intercalated CO can desorb from the Pt surface around room temperature and in UHV, which may promote the CO oxidation confined under graphene. 
650 0 |a Chemistry. 
650 0 |a Physical chemistry. 
650 0 |a Catalysis. 
650 0 |a Surfaces (Physics). 
650 0 |a Interfaces (Physical sciences). 
650 0 |a Thin films. 
650 0 |a Materials  |x Surfaces. 
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