New Carbon-Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C-H Activation

This thesis presents the latest developments in new catalytic C-C bond formation methods using easily accessible carboxylate salts through catalytic decarboxylation with good atom economy, and employing the sustainable element iron as the catalyst to directly activate C-H bonds with high step effici...

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Bibliographic Details
Main Author Shang, Rui (Author)
Corporate Author SpringerLink (Online service)
Format Electronic eBook
LanguageEnglish
Published Singapore : Springer Singapore : Imprint: Springer, 2017.
SeriesSpringer Theses, Recognizing Outstanding Ph.D. Research,
Subjects
Chemistry.
Organometallic chemistry.
Chemistry, Physical and theoretical.
Catalysis.
elektronické knihy
electronic books
Online AccessFull text
ISBN9789811031939
ISSN2190-5053
DOI10.1007/978-981-10-3193-9
Physical Description1 online resource (XVII, 216 p. 163 illus., 7 illus. in color.)

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Table of Contents:
  • Introduction to Carbon-Carbon Coupling Reactions Based on Decarboxylation and Iron-Catalyzed C-H Activation
  • Part I New Carbon-Carbon Bond Formation Methodologies Based on Decarboxylation
  • Transition-Metal-Catalyzed Decarboxylation and Decarboxylative Cross-Couplings
  • Palladium-Catalyzed Decarboxylative Coupling of Potassium Oxalate Monoester with Aryl and Alkenyl Halides
  • Synthesis of Polyfluorobiaryls via Copper-Catalyzed Decarboxylative Couplings of Potassium Polyfluorobenzoates with Aryl Bromides and Iodides
  • Palladium-Catalyzed Decarboxylative Couplings of Potassium Polyfluorobenzoates with Aryl Bromides, Chlorides and Triflates
  • Construction of C(sp3)-C(sp2) Bonds via Palladium-Catalyzed Decarboxylative Couplings of 2-(2-Azaaryl)acetate Salts with Aryl Halides
  • Synthesis of α-Aryl Nitriles and α-Aryl Acetate Esters via Palladium-Catalyzed Decarboxylative Couplings of α-Cyano Carboxylate Salts and Malonate Monoester Salts with Aryl Halides
  • Palladium-Catalyzed Decarboxylative Couplings of Nitrophenyl Acetate Salts and Its Derivatives with Aryl Halides
  • Palladium-Catalyzed Decarboxylative Benzylation of α-Cyano Aliphatic Carboxylate Salts with Benzyl Electrophiles
  • Part II New Carbon-Carbon Bond Formation Methodologies Based on Iron-Catalyzed C-H Activation
  • Recent Develpments of Iron-Catalyzed Directed C-H Activation/C-C Bond Formation Reactions.-β-Arylation of Carboxamides via Iron-Catalyzed C(sp3)-H Bond Activation
  • Iron-Catalyzed C(sp2)-H and C(sp3)-H Bond Functionalization with Organoboron Compounds.

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